AceShowbiz -

Scarlett Johansson did what no other women have ever done before. The "Don Jon" star is named Esquire's Sexiest Woman Alive for a second time in seven years. She becomes the first female to win the title twice. The first time she got the honor was in 2006.

Johansson, 28, is sizzling on the front page of the magazine's latest issue. Perched on the bed, the blonde bombshell is giving a sultry look to the camera and flaunting her curves in a sheer tank top and silky shorts. With sky-high heels on her feet, her mile-long legs look even longer.

"I'm the only woman to win twice right? You know, I gotta hustle. I'm a twenty-eight-year-old woman in the movie business, right? Pretty soon the roles you're offered all become mothers," she jokes. "Then they just sort of stop. I have to hedge against that with work-theater, producing; this thing with Esquire."

The newly-engaged star also talks about her relationship with fiance Romain Dauriac. She credits the French journalist for turning her into a jealous person. "I didn't think I was a jealous person," she opens up, "until I started dating my current, my one-and-only."

The former wife of actor Ryan Reynolds goes on to recount her past romances, "I think maybe in the past I didn't have the same kind of investment. Not that I liked my partner less, I just wasn't capable of it or caring that much."

She adds, "I think jealousy comes with the territory. But I'd rather be with someone who's a little jealous than someone who's never jealous. There's something a little dead fish about them. A little bit depressing. It may not make sense, but you need to feel it a little."

Johansson joins Esquire's previous Sexiest Women Alive like Rihanna (2011), Minka Kelly (2010), Kate Beckinsale (2009), Halle Berry (2008), Charlize Theron (2007), and Jessica Biel (2005). She pushes aside last year's No. 1 Mila Kunis.