The former Disney star sings gloomy lyrics over the haunting piano chords in the short video, reportedly taken during a rehearsal for her performance at Adult Swim's Upfront Party.
De Niro portrays a widower who gets a new job at his 70s and forms an unlikely friendship with his boss, played by Hathaway.
The reality TV star and the music mogul are said to be renewing their vows in Paris, France with the Eiffel Tower as their romantic backdrop.
Also announced to present at the Sunday, May 17 event are Kylie Jenner, Lily Aldridge, Charli XCX, Florida Georgia Line and Prince Royce among others.
Judges Keith Urban, Jennifer Lopez and Harry Connick Jr. team up for a live performance on the Wednesday star-studded finale, which also has Chris Brown, Jamie Foxx and Pitbull as musical guests.
Although Lindsay was said to be 2 hours late, she finally showed up for community service duty on Wednesday at Duffield Children's Center in Brooklyn.
'Supergirl' will air on Monday nights, 'Limitless' TV series joins 'NCIS' duo on Tuesdays, while Jane Lynch's 'Angel From Hell' is added to Thursday comedy block.
The 40-year-old actor just couldn't keep his hands off his model girlfriend as he was seen slipping his hand under her top when they shared passionate kiss.
With 249,000, the British band's new LP also scores the largest sales week for a rock album in almost a year and the third-largest sales week in 2015.
Somerhalder's actress wife Nikki Reed was seen in the Instagram photo wearing a bikini and resting her head on his shoulder.
The 'Fault in Our Stars' director is on board to sit behind the lens and co-write a screenplay that will introduce a group of new mutants.
The Rhonda Lyon depicter shows off her new ring after her DJ boyfriend Devin Lucien popped the question in Paris.
The 'Cesar Chavez' director is circling the role of a rebel fighter while Ben Mendelsohn is expected to play the villain.
The Creed rocker says bipolar disorder coupled with alcohol and drug abuse has led him to a psychotic breakdown.
The 'American Sniper' actor is expected to play a recurring role as Eddie Morra on the new TV series to be directed by Marc Webb.
The Fat Amy of 'Pitch Perfect' movie series says she put her 'unique style and personal loves' into the Rebel for Torrid collection.
CBS will retire 'CSI: Crime Scene Investigation' on September 27 and has enlisted the help of William Petersen and Marg Helgenberger.
The winner of 'American Idol' season 4 dominates this year's pack at the CMT Music Awards, followed by Lady Antebellum and Kenny Chesney.
The 'Blended' actor performs a funny and heartfelt song to bid the 'Late Show with David Letterman' host goodbye before he retires next week.
Britney gives her new alien friend a makeover and cruises around the town with her before eventually taking her to a club.